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Research

Projects and Techniques

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Supercritical Fluid Film Deposition 

The properties of organic semiconductor films are strongly dependent upon their chemical purity and nanoscale morphology. We are developing a unique method for depositing high quality organic semiconductor films from solutions at high temperatures and pressures, very near their critical point.  Pictured at the left is a drawing of our customized pressure chamber. (Drawing courtesy of Mikayla Louie)

In-Situ Spectroscopy of Organic Electrochemical Devices

Organic transistors provide a platform for low-cost printed integrated circuitry. Clarifying the mechanism of carrier transport will improve the design of high performance materials. In-situ infrared experiments provide insight into the role of morphological heterogeneity as a factor limiting the rate of carrier movement.

Data in the figure reproduced from the following publication

Kaake, L.G.; Barbara, P.F.; Zhu, X.Y. Intrinsic Charge Trapping in Organic and Polymeric Semiconductors: A Physical Chemistry PerspectiveJ. Phys. Chem. Lett. 2010, 1, 628-635.

 

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